Whatever material you use the first casting will be the opposite, so if you printed a positive then a negative will be the result. With a relief it doesn't matter much unless there is lettering involved or you are concerned about the direction of the image in the final piece. I have taken to making a solid object of high detail with the first pour using a material called Forton MG. This is a melamine based plaster that creates a ceramic like finish, then I use that solid object as the original casting and make a silicon mold of that for production purposes.
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